研究成果 | 小松研究室

Recruitment

研究成果

原著論文・著書総説

2025 | 2024 | 2023 | 2022 |2021 | 2020 |2019 | 2018 | 2017 | 2016 | 2015 | 2014 | 2013 | 2012 | 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | ~2005

2025

155. G. Cheng, T. Hayashi, X. Fu, N. Komatsu,* "Optical resolution of single-walled carbon nanotubes through wrapping with chiral metal coordination polymers followed by interlocking with metal-tethered tetragonal nanobrackets" Carbon, 2025, 236, 120102. (DOI: 10.1016/j.carbon.2025.120102)
154. P. Qiu, J. Wang, T. Kojima, K. Kazumi, H. Sato, N. Komatsu, K. Fukami, H. Sakaguchi* "Photo-assisted Bottom-up Synthesis of Orange Phosphorus" Angew. Chem. Int. Ed., 2025, 64, e202421571. (DOI: 10.1002/anie.202421571)

2024

153. K. Tanaka, G. Cheng, T. Nakamura, K. Hiraoka, H. Tabata,* O. Kubo, N. Komatsu, M. Katayama, "NH₃ Gas Sensors Based on Single-Walled Carbon Nanotubes Interlocked with Metal-Tethered Tetragonal Nanobrackets" ACS Appl. Nano Mater., 2024, 7, 13417 - 13425. (DOI: 10.1021/acsanm.4c01880)
152. G. Cheng, N. Komatsu,* "Diameter-selective extraction of single-walled carbon nanotubes by interlocking with Cu-tethered square nanobrackets" Beilstein J. Org. Chem., 2024, 20, 1298–1307. (DOI: 10.3762/bjoc.20.113)
151. Y. Zou, Y. Shikano, Y. Nishina, N. Komatsu, E. Kage-Nakadai, M. Fujiwara,* "Size, polyglycerol grafting, and net surface charge of iron oxide nanoparticles determine their interaction and toxicity in Caenorhabditis elegans" Chemosphere, 2024, 358, 142060 (13 pages). (DOI: 10.1016/j.chemosph ere.2024.142060)

2023

150. M. Nishikawa,* J. Yu, H. G. Kang, M. Suzuki, N. Komatsu* "Rational Design, Multistep Synthesis and in Vitro Evaluation of　Poly(glycerol) Functionalized Nanodiamond Conjugated with　Boron-10 Cluster and Active Targeting Moiety for Boron Neutron　Capture Therapy" Chem. Eur. J., 29(63), e202302073 (11 pages) (DOI:10.1002/chem.202302073) [highlighted at the cover, hot paper, open access].

publication_no.150

149. M. Nishikawa,* H. Yagasaki, S. He, N. Komatsu* "Poly(glycerol-co-glyceric acid) Functionalized Nanodiamonds by Nitroxyl Radical-Catalyzed Oxidation of Primary Alcohols in Poly(glycerol) as Scaffolds for Further Conjugation" ChemNanoMat, 9(9), e20230020 (9 pages) (DOI:10.1002/cnma.202300204) [highlighted at the front cover, open access].

publication_no.149

2022

145. Y. Wang, G. Reina, H. G. Kang, X. Chen, Y. Zou, Y. Ishikawa, M. Suzuki, N. Komatsu* "Polyglycerol Functionalized 10B Enriched Boron Carbide Nanoparticle as an Effective Bimodal Anticancer Nanosensitizer for Boron Neutron Capture and Photothermal Therapies" Small, 18(37), 2204044 (2022) (DOI:10.1002/smll.202204044).
144. G. Cheng, T. Hayashi, Y. Miyake, T. Sato, H. Tabata, M. Katayama, N. Komatsu,* "Interlocking of Single-Walled Carbon Nanotubes with Metal-Tethered Tetragonal Nanobrackets to Enrich a Few Hundredths of a Nanometer Range in Their Diameters" ACS Nano, 16(8), 12500-12510 (2022) (DOI:10.1002/acsnano.2c03949).
143. K. Oshimi, Y. Nishimura, T. Matsubara, M. Tanaka, E. Shikoh, L. Zhao, Y. Zou, N. Komatsu, Y. Ikado, Y. Takezawa, E. Kage-Nakadai, Y. Izutsu, K. Yoshizato, S. Morita, M. Tokunaga, H. Yukawa, Y. Baba, Y. Teki and M. Fujiwara,* "Glass-patternable notch-shaped microwave architecture for on-chip spin detection in biological samples" Lab on a Chip, 22(13), 2519-2530 (2022) [highlighted at the inside back cover].
142. Y. Zou, M. Nishikawa, N. Komatsu,* "Organic chemistry for nanodiamond: Controlled functionalization, quantitative characterization and structure-property relationship" Carbon Rep., 1(2), 70-78 (2022).
141. Q.-R. Li, H.-Z. Xu, R.-C. Xiao, Y. Liu, J.-M. Tang, J. Li, T.-T. Yu, B. Liu, L.-G. Li, M.-F. Wang, N. Han, Y.-H. Xu, C. Wang, N. Komatsu, L. Zhao, X.-C. Peng, T.-F. Li,* and X. Chenc,* "Platelets are highly efficient and efficacious carriers for tumor-targeted nano-drug delivery" Drug Delivery, 29(1), 937–949 (2022).
140. Y. Zou, S. Ito, M. Fujiwara, N. Komatsu,* "Probing the role of charged functional groups on nanoparticles grafted with polyglycerol in protein adsorption and cellular uptake" Adv. Funct. Mater., 32(22), 2111077 (15 pages) (2022) [highlighted at the inside front cover].

publication_no.140

2021

139. H. Z. Xu, T.-F. Li, C. Wang, Y. Ma, Y. Liu, M.-Y. Zheng, Z.-J.-Y. Liu, J. B. Chen, K. Li, S.-K. Sun, N. Komatsu, Y.-H. Xu, L. Zhao,* X. Chen,* "Synergy of nanodiamond–doxorubicin conjugates and PD-L1 blockade effectively turns tumor-associated macrophages against tumor cells" J. Nanobiotechnol., 19, 268 (2021).
138. M. Nishikawa,* H. G. Kang, Y. Zou, H. Takeuchi, N. Matsuno, M. Suzuki, N. Komatsu* "Conjugation of Phenylboronic Acid Moiety through Multistep Organic Transformations on Nanodiamond Surface for an Anticancer Nanodrug of Boron Neutron Capture Therapy" Bull. Chem. Soc. Jpn., 94(9), 2302-2312 (2021) [selected paper, highlighted at the inside cover, open access].

publication_no.138

137. Y. Zou, M. Nishikawa, H. G. Kang, G. Cheng, W. Wang, Y. Wang, N. Komatsu,* "Effect of Protein Corona on Mitochondrial Targeting Ability and Cytotoxicity of Triphenylphosphonium Conjugated with Polyglycerol-Functionalized Nanodiamond" Mol. Pharmaceutics, 18(7), 2823-2832 (2021).
136. S-J. Yuan, C. Wang, H. Z. Xu, Y. Liu, M.-Y. Zheng, K. Li, S.-K. Sun, N. Komatsu, L. Zhao,* X. Chen,* "Conjugation with nanodiamonds via hydrazone bond fundamentally alters intracellular distribution and activity of doxorubicin" Int. J. Pharm., 606, 120872 (2021).
135. V. L. J. Joly,* K. Takai,* M. Kiguchi, N. Komatsu, T. Enoki,* "Anomalous spin relaxation in graphene nanostructures on the high temperature annealed surface of hydrogenated diamond nanoparticles" Phys. Chem. Chem. Phys, 23 (35), 19209-19218 (2021) [selected as a PCCP hot article].

2020

134. W. Wang, Y. Zou, A. López-Moreno, Y. Jiang, F. Wen, H. X. Wang, N. Komatsu,* "Hydrophobic Surface Coating of Nanodiamond by Polyglycerol-Based Polymers with Alkyl Chains for Dispersing in an Organic Solvent" ChemNanoMat, 6(9), 1332-1336 (2020). [highlighted at the front cover].
133. M. Fujiwara,* S. Sun, A. Dohms, Y. Nishimura, K. Suto, Y. Takezawa, K. Oshimi, L. Zhao, N. Sadzak, Y. Umehara, Y. Teki, N. Komatsu, O. Benson, Y. Shikano,* and E. Kage-Nakadai* "Real-time nanodiamond thermometry probingin-vivothermogenic responses" Sci. Adv., 6, eaba9636 (2020).
132. Y. Zou, S. Ito, F. Yoshino, Y. Suzuki, L. Zhao, N. Komatsu,* "Polyglycerol Grafting Shields Nanoparticle from Protein Corona Formation to Avoid Macrophage Uptake" ACS Nano, 14 (6), 7216-7226 (2020).
131. 小松直樹, "ナノ粒子を用いたがんの治療および診断ーいかにタンパク質コロナを制御するか（最新のトピックス）" 化学, 75(5), 76-77 (2020).
130. Y. Zou, N. Komatsu,* "Quantitative investigation of the interaction between proteins and charged functional groups on the polyglycerol-grafted nanodiamond surface" Carbon, 163, 395-401 (2020).
129. A. Bianco,* N. Komatsu, Y. Chen, Editorial Introduction for the Virtual Special Issue (VSI) entitled “Carbon Material Bio-interfaces” Carbon, 163, 253 (2020).
128. N. Komatsu, "Chemical Functionalization of Nanodiamond for Nanobiomedicine" Funtionalization of Nanocarbons; J.-C. Arnault and D. Eder, Eds.; Wiley: Chapter 7, pp 229-245 (2020).
127. Z. Chen, S.-J. Yuan,K. Li, Q. Zhang, T.-F. Li, H.-C. An, H.-Z. Xu, Y. Yue, M. Han, Y. H. Xu, N. Komatsu, L. Zhao,* X. Chen,* "Doxorubicin-polyglycerol-nanodiamond conjugates disrupt STAT3/IL-6-mediated reciprocal activation loop between glioblastoma cells and astrocytes" J. Control. Release, 320, 469-483 (2020).
126. A. Lopez Moreno,* Y. Jiang, G. Cheng, N. Komatsu* "Extraction of carbon nanotubes with porphyrin- and pyrene-based nanotweezers and nanocalipers: Insight from the association constants" J. Porphyrins Phthalocyanines, 24 (1-3), 314-319 (2020).

2019

125. A. Tayyebi, N. Ogino, T. Hayashi, N. Komatsu* "Size-controlled MoS2 nanosheet through ball milling exfoliation: parameter optimization, structural characterization and electrocatalytic application" Nanotechnology, 31(7), 075704 (2019).
124. G. Liu,* P. Zhao, N. Liu, F. Yoshino, H. Qin, Y. Zou, S. Shi, T. Amano, J. R. Aguilar Cosme, Y. Nagano, H. Tamiaki, N. Komatsu* "Photosensitizer and anticancer drug-loaded 2D nanosheet: Preparation, stability and anticancer property" 2D Materials, 6(4), 045035 (2019).
123. G. Reina, L. Zhao, A. Bianco,* N. Komatsu,* "Chemical functionalization of nanodiamonds: opportunities and challenges ahead" Angew. Chem. Int. Ed., 58 (50), 17918-17929 (2019).
122. F. Yoshino, T. Amano, Y. Zou, J. Xu, F. Kimura, Y. Furusho, T. Chano, T. Murakami, L. Zhao,* N. Komatsu,* "Preferential tumor accumulation of polyglycerol functionalized nanodiamond conjugated with cyanine dye leading to near infrared fluorescence in vivo tumor imaging" Small, 15(48), 1901930 (2019). [highlighted at the back cover].
121. 小松直樹, "私にとってのBN（巻頭言）" New Diamond, 35(2), 1-2 (2019).
120. K. Nagura, A. Bogdanov, N. Chumakova, A. Kh. Vorobiev, S. Moronaga, H. Imai, T. Matsuda, Y. Noda, T. Maeda, S. Koizumi, K. Sakamoto, T. Amano, F. Yoshino, T. Kato, N. Komatsu,* and R. Tamura,* "Size-tunable MRI-visible nitroxide-based magnetic mixed micelles: preparation, stability, and theranostic application" Nanotechnology, 30(22), 224002 (2019).
119. K. Nagura, Y. Takemoto, F. Yoshino, A. Bogdanov, N. Chumakova, A. Kh. Vorobiev, H. Imai, T. Matsuda, S. Shimono, T. Kato, N. Komatsu,* and R. Tamura,* "Magnetic Mixed Micelles Composed of a Non-Ionic Surfactant and Nitroxide Radicals Containing a D-Glucosamine Unit: Preparation, Stability, and Biomedical Application" Pharmaceutics, 11(1), 42 (2019).
118. N. Komatsu, "Various surfactants for 0 – 3 dimensional nanocarbons: Separation, exfoliation and solubilization (minireview)" Adv. Mater. Lett., 10(8), 520-523 (2019).
117. Z. Chen, C. Wang, T.-F. Li, K. Li, Y. Yue, X. Liu, H. Z. Xu, Y. Wen, Q. Zhang, M. Han, N. Komatsu, Y. H. Xu, L. Zhao,* X. Chen,* "Doxorubicin conjugated with nanodiamonds and in free form commit glioblastoma cells to heterodromous fates" Nanomedicine (Lond), 14(3), 335-351 (2019).
116. T.-F. Li, Y.-H. Xu, K. Li, . Wang, X. Liu, Y. Yue, Z. Chen, S.-J. Yuan, Y. Wen, Q. Zhang, M. Han, N. Komatsu, L. Zhao,* X. Chen,* "Doxorubicin-polyglycerol-nanodiamond composites stimulate glioblastoma cell immunogenicity through activation of autophagy" Acta Biomaterialia, 86, 381-394 (2019).
115. S.-J. Yuan, Y.-H. Xu, C. Wang, H.-C. An, H. Z. Xu, K. Li, N. Komatsu, L. Zhao,* X. Chen,* "Doxorubicin-polyglycerol-nanodiamond conjugate is a cytostatic agent that evades chemoresistance and reverses cancer-induced immunosuppression in triple-negative breast cancer" J. Nanobiotechnol., 17, 110 (25 pages) (2019).

2018

114. T.-F. Li, K. Li, Q. Zhang, C. Wang, Y. Yue, Z. Chen, S.-J. Yuan, X. Liu, Y. Wen, M. Han, N. Komatsu, Y.-H. Xu⁠, L. Zhao,* X. Chen,* "Dendritic cell-mediated delivery of doxorubicin-polyglycerol-nanodiamond composites elicits enhanced anti-cancer immune response in glioblastoma" Biomaterials, 181, 35-52 (2018).
113. G. Liu, N. Liu, A. López-Moreno, P. Zhao, W. Dai, S. Shi, N. Komatsu, "Efficient Production of Single-Walled Carbon Nanotube Aqueous Dispersion Using Hexahydroxytriphenylene as a Dispersant and Stabilizer" ChemistrySelect, 3 (22), 6081-6086 (2018).
112. N. Komatsu, "Functionalized Carbon Nanomaterials for Drug Delivery" Carbon Nanomaterials for Bioimaging, Bioanalysis and Therapy; H.-C. Chang, Y. Y. Hui, H. Dong and X. Zhang, Eds.; Wiley: Chapter 10, pp 267-288 (2018).
111. C. Wang, K. Li, T.-F. Li⁠⁠, Z. Chen⁠⁠, Y. Wen⁠⁠, X. Liu, X. Jia, Y. Zhang, Y.-H. Xu⁠, M. Han⁠, N. Komatsu, L. Zhao,* X. Chen,* "Monocyte-mediated chemotherapy drug delivery in glioblastoma" Nanomedicine, 13(2):157-178 (2018).
110. Y. Miyake, A. López-Moreno, J. Yang, H.-J. Xu, N. Desbois, C. P. Gros, N. Komatsu, "Synthesis of flexible nanotweezers with various metals and their application to carbon nanotube extraction" New J. Chem., 42(10), 7592-7594 (2018) [highlighted at the back cover].

2017

109. 小松直樹, "ナノカーボンの interface: 活性化と分離”, C & I Commun., 42 (4), 21-23 (2017).
108. T.-F. Li, K. Li, C. Wang, X. Liu, Y. Wen, Y.-H. Xu, Q. Zhang, Q.-Y. Zhao, M. Shao, Y.-Z. Li, M. Han, N. Komatsu, L. Zhao,* X. Chen,* "Harnessing the cross-talk between tumor cells and tumor-associated macrophages with a nano-drug for modulation of glioblastoma immune microenvironment" J. Control. Release, 268, 128-146 (2017).
107. K. Nagura, Y. Takemoto, S. Moronaga, Y. Uchida, S. Shimono, A. Shiino, K. Tanigaki, T. Amano, F. Yoshino, Y. Noda, S. Koizumi, N. Komatsu, T. Kato, J. Yamauchi, R. Tamura* "Preparation of robust metal-free magnetic nanoemulsions encapsulating low-molecular-weight nitroxide radicals and hydrophobic drugs directed toward MRI-visible targeted delivery" Chem. Eur. J., 23 (62), 15713–15720 (2017).
106. G. Liu, Y. Miyake, N. Komatsu* "Nanocalipers as novel molecular scaffolds for carbon nanotubes " Org. Chem. Front., 4 (5), 911-919 (2017).
105. X. Li, L. Zhao, J. Ye, Q. Liang, M. Xu, N. Komatsu,* G. Yuan, Q. Zhang, W. Gao, X. Chen,* "Cationic Polyarginine Conjugated Mesoporous Bioactive Glass Nanoparticles with Polyglycerol Coating for Efficient DNA Delivery" J. Biomed. Nanotechnol., 13 (3), 280-289 (2017).
104. J.-M. Levêque, L. Duclaux, J.-N. Rouzaud, L. Reinert, N. Komatsu, A. Desforges, S. Afreen, M. Sivakumar, T. Kimura "Ultrasonic treatment of glassy carbon for nanoparticle preparation" Ultrason. Sonochem., 35 (B), 615-622 (2017).

2016

103. L. Zhao, H. Yang, T. Amano, H. Qin, L. Zheng, A. Takahashi, S. Zhao, I. Tooyama, T. Murakami, N. Komatsu,* "Efficient Delivery of Chlorin e6 into Ovarian Cancer Cell with Octalysine Conjugated Superparamagnetic Iron Oxide Nanoparticle for Effective Photodynamic Therapy" J. Mater. Chem. B, 4(47), 7741-7748 (2016).
102. H. Qin, K. Maruyama, T. Amano, T. Murakami, N. Komatsu,* "Hyperbranched polyglycerol-grafted titanium oxide nanoparticles: Synthesis, derivatization, characterization, size separation, and toxicology" Mater. Res. Express, 3 (10), 105049 (2016).
101. 小松直樹, "光ってる　ダイヤモンドを　生体に", 光技術コンタクト, 54 (8), 12-19 (2016).
100. N. Komatsu, L. Zhao, "Polyglycerol-Functionalized Nanoparticles for Biomedical Imaging" Carbon Nanoparticles and Nanostructures; N. Yang, X. Jiang, D.-W. Pang, Eds.; Springer: Chapter 5, pp. 139-159 (2016).
99. G. Liu, N. Komatsu* "Readily available "stock solid" of MoS2 and WS2 nanosheets through solid phase exfoliation for highly concentrated dispersion in water" ChemNanoMat, 2 (6), 500 - 503 (2016) [highlighted at the front cover and spotlights on our sister journals in Angew. Chem. Int. Ed., 35 (33), 9467 (2016)].
98. G. Liu, N. Komatsu* "An efficient and scalable production of 2D material dispersions using hexahydroxytriphenylene as a versatile exfoliant and dispersant" ChemPhysChem, 17 (11), 1557–1567 (2016) [highlighted at the front cover and the cover profile].

2015

97. G. Liu, H. Qin, T. Amano, T. Murakami, and N. Komatsu,* "Direct Fabrication of the Graphene-Based Composite for Cancer Phototherapy through Graphite Exfoliation with a Photosensitizer" ACS Appl. Mater. Interfaces, 7 (42), 23402-23406 (2015).
96. L. Zhao, and N. Komatsu,* "Surface Functionalization of Nanodiamond for Biomedical Applications: Polyglycerol Grafting and Further Derivatization" Chemical Functionalization of Carbon Nanomaterials: Chemistry and Applications; V. K. Thakur and M. K. Thakur, Eds.; CRC Press: Chapter 28, pp. 650-663 (2015).
95. M. Fujita,* J.-M. Lévêque, N. Komatsu, and T. Kimura, "Sono-bromination of aromatic compounds based on the ultrasonic advanced oxidation processes", Ultrason. Sonochem., 27, 247-251 (2015).
94. 小松直樹, "ナノダイヤモンドのドラッグキャリア、イメージングプローブへの応用", New Diamond, 31 (2), 16-18 (2015).
93. L. Zhao, A. Shiino, H. Qin, T. Kimura, and N. Komatsu,* "Synthesis, Characterization, and Magnetic Resonance Evaluation of Polyglycerol-Functionalized Detonation Nanodiamond Conjugated with Gadolinium(III) Complex", J. Nanosci. Nanotechnol., 15 (2), 1076-1082 (2015).

2014

92. Gang Liu, Yukie Saito, Daisuke Nishio-Hamane, Ajoy K Bauri, Emmanuel Flahaut, Takahide Kimura and Naoki Komatsu* "Structural Discrimination of Double-Walled Carbon Nanotubes by Chiral Diporphyrin Nanocalipers", J. Mater. Chem. A, 2 (44), 19067-19074 (2014).
91. L. Zhao, Y.-H. Xu, H. Qin, S. Abe, T. Akasaka, T. Chano, F. Watari, T. Kimura, N. Komatsu,* and X. Chen* "Platinum on Nanodiamond: A Promising Prodrug Conjugated with Stealth Polyglycerol, Targeting Peptide, and Acid-Responsive Antitumor Drug" Adv. Funct. Mater., 24 (34), 5348-5357 (2014) [highlighted at the inside front cover].
90. L. Zhao, Y.-H. Xu, T. Akasaka, S. Abe, N. Komatsu, F. Watari, and X. Chen* "Polyglycerol-coated Nanodiamond as a macrophage-evading platform for selective drug delivery in cancer cells" Biomaterials, 35 (20), 5393-5406 (2014).
89. L. Zhao, Y. Nakae, H. Qin, T. Ito, T. Kimura, H. Kojima, L. Chan, and N. Komatsu,* "Polyglycerol-Functionalized Nanodiamond as a Platform for Gene Delivery: Derivatization, Characterization, and Hybridization with DNA", Beilstein J. Org. Chem., 10, 707-713 (2014).
88. N. Fuyuno, D. Kozawa, Y. Miyauchi, S. Mouri, R. Kitaura, H. Shinohara, T. Yasuda, N. Komatsu, and K. Matsuda,* "Drastic Change in Photoluminescence Properties of Graphene Quantum Dots by Chromatographic Separation", Adv. Opt. Mater., 2 (10), 983–989 (2014).
87. M. Fujita,* N. Komatsu, and T. Kimura, "Sonochemical preparation of carbon spheres", Ultrason. Sonochem., 21 (3), 943-945 (2014).
86. 村井亮太，高谷裕浩，林照剛，道畑正岐，小松直樹, "ポリグリセロール修飾ナノダイヤモンドを用いた銅膜の平坦化加工に関する研究", 砥粒加工学会誌, 58 (2), 97-102 (2014) [平成26年度砥粒加工学会賞論文賞].
85. L. Zhao, and N. Komatsu,* "Synthesis, Size Separation, Characterization and Surface Engineering of Superparamagnetic Iron Oxide Nanoparticles for Biomedical Applications" Magnetic Nanoparticles: Synthesis, Physicochemical Properties and Role in Biomedicine; N. P. Sabbas, Ed.; Nova Science Publishers, Inc.: New York, Chapter 4, pp. 94-112 (2014).
84. 高谷裕浩，村井亮太，林照剛，道畑正岐，小松直樹, "化学修飾ナノダイヤモンドを用いた銅薄膜表面の化学機械研磨", New Diamond, 30 (2), 25-27 (2014).
83. N. Komatsu, "ナノダイヤモンドの臨床応用を目指して", New Diamond, 30 (1), 16-19 (2014).
82. N. Komatsu, "Separation of left- and right-handed carbon nanotubes", Symmetry: Culture and Science, 25 (2), 87-90 (2014).
81. 小松直樹, "超音波で分離した環状カーボンナノチューブ", 空気清浄, 52 (1), 57 (2014).

2013

80. G. Liu, A. F. M. M. Rahman, S. Chaunchaiyakul, T. Kimura, Y. Kuwahara, and N. Komatsu,* "Bis(tert-butylpyrene) Nanotweezers and Nanocalipers: Enhanced Extraction and Recognition Abilities for Single-Walled Carbon Nanotubes", Chem. Eur. J., 19 (48), 16221-16230 (2013) [highlighted at the front cover].
79. T. Irie, K. Oda, A. Shiino, M. Kubo, S. Morikawa, N. Urushiyama, S. Aonuma, T. Kimura, T. Inubushi, T. Oohashi, and N. Komatsu,* "Design, synthesis, and preliminary ex vivo and in vivo evaluation of cationic magnetic resonance contrast agent for rabbit articular cartilage imaging", Med. Chem. Commun., 4 (11), 1508-1512 (2013).
78. Y. Li, A. F. M. M. Rahman, G. Liu, Z. Xiong, K. Koezuka, Z. Xu, N. Komatsu and F. Wang,* "Enrichment of Large-Diameter Single-Walled Carbon Nanotubes (SWNTs) with Metallo-Octaethylporphyrins", Materials, 6 (8), 3064-3078 (2013).
77. G. Liu, F. Wang, S. Chunchaiyakul, Y. Saito, A. K. Bauri, T. Kimura, Y. Kuwahara, and N. Komatsu,* "Simultaneous Discrimination of Diameter, Handedness, and Metallicity of Single-Walled Carbon Nanotubes with Chiral Diporphyrin Nanocalipers", J. Am. Chem. Soc., 135 (12), 4805-4814 (2013) [highlighted in Chemical & Engineering News, 91 (12), p. 34, March 25, 2013].
76. T. Yasumitsu, G. Liu, J.-M. Leveque, S. Aonuma, L. Duclaux, T. Kimura,* and N. Komatsu,* "A rosette cooling cell: more effective container for solubilization of single-walled carbon nanotubes under probe-type ultrasonic irradiation" Ultrason. Sonochem., 20 (1), 37-39 (2013).
75. 小松直樹、"ロゼッタ型冷却容器を用いた単層カーボンナノチューブの分散", ケミカルエンジニアリング, 58 (4), 66-69 (2013).
74. 小松直樹、"ナノ炭素材料化学における超音波", 超音波テクノ, 25 (1), 10-14 (2013).

2012

73. L. Zhao, T. Chano, S. Morikawa, Y. Saito, A. Shiino, S. Shimizu, T. Maeda, T. Irie, S. Aonuma, H. Okabe, T. Kimura, T.Inubushi, and N. Komatsu,* "Hyperbranched Polyglycerol-Grafted Superparamagnetic Iron Oxide Nanoparticles: Synthesis, Characterization, Functionalization, Size Separation, Magnetic Properties, and Biological Applications" Adv. Funct. Mater., 22 (24), 5107-5117 (2012).
72. G. Liu, T. Yasumitsu, L. Zhao, X. Peng, F. Wang, A. K. Bauri, S. Aonuma, T. Kimura, and N. Komatsu,* "Preferential extraction of left- or right-handed single-walled carbon nanotubes by use of chiral diporphyrin nanotweezers" Org. Biomol. Chem., 10 (30), 5830-5836 (2012) [highlighted at the inside front cover].
71. X. Peng,* H. Qin, L. Li, Y. Huang, J. Peng, Y. Cao, and N. Komatsu, "Water redissoluble chiral porphyrin-carbon nanotube composites" J. Mater. Chem., 22 (12), 5764-5769 (2012).
70. G. Liu, F. Wang, X. Peng, A. F. M. M. Rahman, A. K. Bauri, and N. Komatsu,* "Separation of Left- and Right-Handed Structures of Single-Walled Carbon Nanotubes through Molecular Recognition" Handbook of Biomedical Applications of Carbon Nanomaterials; K. M. Kadish and F. D'souza, Eds.; World Scientific: vol. 3, pp. 203-232 (2012).

2011

69. M. Dubois,* K. Guerin, N. Batisse, E. Petit, A. Hamwi, N. Komatsu, H. Kharbache, P. Pirotte, and F. Masin, "Solid State NMR study of nanodiamond surface chemistry" Solid State Nuclear Magnetic Resonance, 40 (4), 144-154 (2011).
68. L. Zhao, T. Takimoto, T. Kimura, and N. Komatsu,* "Polyglycerol functionalization of ZnO nanoparticles for stable hydrosol in physiological media" J. Indian Chem. Soc., 88, December, 1787-1790 (2011).
67. F. Wang, K. Matsuda, A. F. M. M. Rahman, T. Kimura, and N. Komatsu,* "Improved selectivity in discriminating handedness and diameter of single-walled carbon nanotubes with N-substituted 3,6-carbazolylene-bridged chiral diporphyrin nanotweezers" Nanoscale, 3 (10), 4117-4124 (2011) [highlighted at the inside front cover].
66. A. F. M. M. Rahman, F. Wang, K. Matsuda, T. Kimura, and N. Komatsu,* "Diameter-based separation of single-walled carbon nanotubes through selective extraction with dipyrene nanotweezers" Chem. Sci., 2 (5), 862-867 (2011) [highlighted at the inside front cover].
65. L. Zhao, T. Takimoto, M. Ito, N. Kitagawa, T. Kimura, and N. Komatsu,* "Chromatographic Separation of Highly Soluble Diamond Nanoparticles Prepared by Polyglycerol Grafting" Angew. Chem. Int. Ed., 50 (6), 1388-1392 (2011) [highlighted at back cover].
64. J.-M. Leveque, M. Fujita, A. Bosson, H. Sohmiya, C. Petrier, N. Komatsu, and T. Kimura* "Secondary sonochemical effect on Mo-catalyzed bromination of aromatic compounds" Ultrason. Sonochem., 18 (3), 753-756 (2011).
63. D. Pal. M. Furukawa, N. Komatsu, H. Uno,* and S. Bhattacharya,* "Photophysical insights into supramolecular interaction of a designed bisporphyrin with fullerenes C60 and C70", Spectrochimica Acta A, 78 (1), 185-190 (2011).
62. 小松　直樹、”バイオテクノロジーにおける炭素材料の未来”, New Diamond, 27 (1), 100号記念号、68-70 (2011).

2010

61. X. Peng,* Y. Huang, C. Gao, J. Peng, N. Komatsu, A. Osuka, and Y. Cao, "Macroscopic films of porphyrin nanowell-arrays via solvent diffusion-induced self-assembly", J. Phys. Chem. C, 114 (43), 18449-18454 (2010).
60. F. Wang, K. Matsuda, A. F. M. M. Rahman, X. Peng, T. Kimura, and N. Komatsu,* "Simultaneous Discrimination of Handedness and Diameter of Single-Walled Carbon Nanotubes (SWNTs) with Chiral Diporphyrin Nanotweezers Leading to Enrichment of Single Enantiomer of (6,5)-SWNTs", J. Am. Chem. Soc., 132 (31), 10876-10881 (2010).
59. T. Takimoto, T. Chano, S. Shimizu, H. Okabe, M. Ito, M. Morita, T. Kimura, T. Inubushi, and N. Komatsu,* “Preparation of Fluorescent Diamond Nanoparticles Stably Dispersed under a Physiological Environment through Multi-Step Organic Transformations”, Chem. Mater., 22 (11), 3462-3471 (2010).
58. N. Komatsu, "Stereochemistry of Carbon Nanotubes", Jpn. J. Appl. Phys., special issue, 49 (2), 02BC01 (2010).
57. 小松　直樹、”ナノ炭素材料（カーボンナノチューブ、ナノダイヤモンド）を仕分ける”, 粉体技術, 2 (11), 28-36 (2010).
56. X. Peng, F. Wang, A. F. M. M. Rahman, A. Bauri, and N. Komatsu,*"Optical Resolution of Single-Walled Carbon Nanotubes through Molecular Recognition with Chiral Diporphyrin Nanotweezers", Chem. Lett. (Highlight Review), 39 (10), 1022-1027 (2010).
55. N. Komatsu,* and F. Wang, "A Comprehensive Review on Separation Methods and Techniques for Single-Walled Carbon Nanotubes", Materials (open access journal), 3 (7), 3818-3844 (2010).

2009

54. X. Peng, F. Wang, T. Kimura, N. Komatsu,* and A. Osuka, "Optical Resolution and Diameter-Based Enrichment of Single-Walled Carbon Nanotubes through Simultaneous Recognition of Their Helicity and Diameter with Chiral Monoporphyrin", J. Phys. Chem. C., 113 (21), 9108-9113 (2009).
53. M. Dubois,* K. Guerin, E. Petit, N. Batisse, A. Hamwi, N. Komatsu, J. Giraudet, P. Pirotte, and F. Masin,* "Solid State NMR Study of Nanodiamonds Produced by Detonation Technique", J. Phys. Chem. C. 113 (24), 10371-10378 (2009).
52. 瀧本竜哉、森田陽一、門田直樹、青沼秀児、木村隆英、小松直樹、"医療応用を目指したナノダイヤモンドの表面官能基化とサイズ分離", ケミカルエンジニアリング, 54 (12), 947-951 (2009).
51. 小松　直樹、”ナノダイヤモンドの医学的応用”, 機能材料, 29 (6), 23-29 (2009).
50. 小松　直樹、”生物・医療応用を目指したナノダイヤモンド粒子のサイズ分離と表面化学修飾”, 表面科学, 30 (5), 273-278 (2009).
49. N. Komatsu, "Novel and Practical Separation Processes for Fullerenes, Carbon Nanotubes and Nanodiamonds" J. Jpn. Petrol. Inst., 52 (3), 73-80 (2009).

2008

48. Y. Morita, T. Takimoto, H. Yamanaka, K. Kumekawa, S. Morino, S. Aonuma, T. Kimura, and N. Komatsu,*"A Facile and Scalable Process for Size-Controllable Separation of Nanodiamond as Small as 4 nm", Small, 4 (12), 2154-2157 (2008).
47. X. Peng, N. Komatsu,* T. Kimura, and A. Osuka, "Simultaneous Enrichments of Optical Purity and (n, m) Abundance of SWNTs through Extraction with 3,6-Carbazolylene-Bridged Chiral Diporphyrin Nanotweezers", ACS Nano, 2 (10), 2045-2050 (2008).
46. A. F. M. M. Rahman, S. Bhattacharya, Xiaobin Peng, Takahide Kimura, and N. Komatsu, "Unexpectedly Large Binding Constants of Azulenes with Fullereenes”, Chem. Commun., 1196-1198 (2008).
45. S. Bhattacharya,* M. Hashimoto, A. Fujimoto, T. Kimura, H. Uno, and N. Komatsu,"Photophysical properties of a novel Ni(II)-Diporphyrin in Presence of Fullerenes: Insights from Experimental and Theoretical Studies", Spectrochimica Acta A, 70 (2), 416-424 (2008).
44. N. Komatsu, "Separation of Nanocarbons by Molecular Recognition" J. Incl. Phenom. Macrocycl. Chem., 61, 195-216 (2008) [highlighted at cover picture].
43. N. Komatsu, "Heterocyclic Supramolecular Chemistry of Fullerenes and Carbon Nanotubes" Topics in Heteroatom Chemistry; K. Matsumoto, Ed.; Springer: Heidelberg, Germany, pp 161-198 (2008).
42. 小松　直樹、”光学活性カーボンナノチューブ”, New Diamond, 24 (1), 26-27 (2008).

2007

41. X. Peng, N. Komatsu,* T. Kimura, and A. Osuka, "Improved Optical Enrichment of SWNTs through Extraction with Chiral Nano-tweezers of 2,6-Pyridylene-bridged Diporphyrins", J. Am. Chem. Soc., 129 (51), 15947-15953 (2007).
40. X. Peng, N. Komatsu,* S. Bhattacharya, T. Shimawaki, S. Aonuma, T. Kimura, and A. Osuka, "Optically Active Single-Walled Carbon Nanotubes", Nature Nanotechnology, 2 (6), 361-365 (2007) [highlighted in Chemical & Engineering News (May 14, p. 41, 2007), Materials Today (10 (7-8), p. 13, 2007) and Kagaku (62 (7), p. 75, 2007)].
39. N. Komatsu,* N. Kadota, T. Kimura, and E. Osawa, "Solution-phase 13C-NMR Spectroscopy of Detonation Nanodiamond", Chem. Lett. 36 (3), 398-399 (2007).
38. S. Bhattacharya,* K. Tominaga, T. Kimura, H. Uno* and N. Komatsu* "A new metalloporphyrin dimer: effective and selective molecular tweezers for fullerenes" Chem. Phys. Lett., 433 (4-6), 395-402 (2007).
37. N. Komatsu,* N. Kadota, T. Kimura, Y. Kikuchi and M. Arikawa "Remarkable Improvement in Efficiency of Filtration Method for Fullerene Purification" Fullerenes, Nanotubes and Carbon Nanostructures, 15 (4), 217-226 (2007).
36. S. Bhattacharya,* N. Ujihashi, S. Aonuma, T. Kimura, and N. Komatsu,*"Spectral and theoretical studies on effective and selective non-covalent interaction between tetrahexylporphyrins and fullerenes" Spectrochimica Acta A, 68 (3), 495-503 (2007).
35. 島脇　孝典、青沼　秀児、木村　隆英、小松　直樹、”モノポルフィリン化合物による単層カーボンナノチューブの可溶化” 滋賀医科大学基礎学紀要, 13, 45-52 (2007).
34. 小松　直樹、”超音波霧化を利用した環状カーボンナノチューブの濃縮分離　＝超音波霧化による濃縮手法の固液不均一系への応用＝”, 超音波テクノ, 19 (5), 63-66 (2007).
33. 小松　直樹、”ダイヤモンド技術総覧”ダイヤモンド工業協会編、NGTコーポレーション、第９章、３・７　医療応用、683-687 (2007)

2006

32. S. Bhattacharya,* T. Shimawaki, X. Peng, A. Ashokkumar, S. Aonuma, T. Kimura, and N. Komatsu,* "Spectroscopic and Theoritical Investigations on Effective and Selective Complexation between Porphyrins and Fullerenes" Chem. Phys. Lett., 430 (4-6), 435-442 (2006).
31. N. Komatsu,* T. Shimawaki, S. Aonuma and T. Kimura, "Ultrasonic Isolation of Toroidal Aggregates of Single-Walled Carbon Nanotubes" Carbon, 44 (10), 2091-2093 (2006).
30. 小松　直樹、”ナノ医療を目指したナノ炭素材料科学” ケミカルエンジニアリング, 51 (12), 941-944 (2006).
29. 小松　直樹、門田　直樹、木村　隆英、”ナノダイヤモンドの表面化学修飾とその物性に与える影響” New Diamond, 22 (4), 24-25 (2006).

-2005

28. S. Bhattacharya,* N. Komatsu, M. Banerjee, "pai-Electronic Charge-Transfer Interactions in Supramolecular Complex Formation between Fullerenes and 5,10,15,20-Tetrahexylporphyrin" Chem. Phys. Lett., 406 (4-6), 509-518 (2005).
27. N. Komatsu,* T. Ohe, and Kazumi Matsushige "A Highly Improved Method for Purification of Fullerenes Applicable to Large-scale Production" Carbon, 42, 163-167 (2004).
26. N. Komatsu, "Preferential Precipitation of C70 over C60 with p-Halohomooxacalix[3]arenes" Org. Biomol. Chem., 1(1), 204-209 (2003).
25. 小松　直樹、”フラーレンの分離精製－世界最強法への道程と特許戦略－”ペトロテック(石油学会誌)、26(5), 373-378(2003).
24. N. Komatsu, "New Synthetic Route to Homooxacalix[n]arenes via Reductive Coupling of Diformylphenols" Tetrahedron Lett., 42(9), 1733-1736 (2001).
23. N. Komatsu,* and T. Chishiro, "Serial Synthesis of Oxa[3.n]cyclopanes and Homooxacalix[n]arenes via Reductive Coupling of Arenedialdehydes, and Their X-ray Structures" J. Chem. Soc., Perkin Trans. 1, (13), 1532-1537 (2001).
22. N. Komatsu,* A. Taniguchi, S. Wada, and H. Suzuki, "A Catalytic Deprotection of S,S-, S,O- and O,O-Acetals Using Bismuth(III) Nitrate under Air" Adv. Synth. Catal., 343(5), 473-480 (2001).
21. N. Komatsu, "Bismuth Compounds in Organic Transformations" Organobismuth Chemistry; H. Suzuki and Y. Matano, Eds.; Elsevier: Lausanne, Switzerland, Chapter 5, 371-440 (2001).
20. N. Komatsu,* A. Taniguchi, and H. Suzuki, "Homooxacalix[n]thiophenes: Their One-pot Serial Synthesis and X-ray Structures" Tetrahedron Lett., 40(19), 3749-3752 (1999).
19. N. Komatsu,* M. Uda, and H. Suzuki,* "Air Oxidation of Sufides to Sulfoxides Using BiBr3-Bi(NO3)3 as a Binary Catalyst" Chem. Lett., (12), 1229-1230 (1997).
18. N. Komatsu,* J. Ishida, and H. Suzuki, "Bismuth Bromide-Catalyzed Reductive Coupling of Carbonyl Compounds and Its Application to the Synthesis of Novel Crownophanes" Tetrahedron Lett., 38(41), 7219-7222 (1997).
17. N. Komatsu,* M. Uda, H. Suzuki,* T. Takahashi, T. Domae, and M. Wada,* "Bismuth Bromide as an Efficient and Versatile Catalyst for the Cyanation and Allylation of Carbonyl Compounds and Acetals with Organosilicon Reagents" Tetrahedron Lett., 38(41), 7215-7218 (1997).
16. N. Komatsu,* A. Taniguchi, M. Uda, and H. Suzuki,* "A Novel Method for the Deprotection of S,S-acetals Using Air and a Catalytic Amount of Bismuth(III) Nitrate" Chem. Commun., (15), 1847-1848 (1996).
15. N. Komatsu,* M. Uda, and H. Suzuki,* "Bismuth(III) Halides and Sulfate as Highly Efficient Catalyst for the Sulfenylation of Carbonyl and Related Compounds" Synlett, (9), 984-986 (1995).
14. 小松　直樹、植村　榮、”有機カルコゲン化学の不斉合成への展開－最近の進歩を中心に－”有機合成化学協会誌、53(4), 268-274 (1995).
13. N. Komatsu, and S. Uemura, "Synthetic and Mechanistic Aspects of Asymmetric Reactions of Organoselenium Compounds" Advances in Detailed Reaction Mechanism; James M. Coxon, Ed.; Jai Press: Greenwich, CT, Vol. 4, pp 73-92 (1995).
12. H. Tanaka, S. Sumida, N. Kobayashi, N. Komatsu, and S. Torii,* "Use of Aluminum as an Electron Pool. Reductive Coupling of Aryl Halides Promoted by Electron Transfer in an Ni/Pb/Al Multi Redox System" Inorg. Chim. Acta, 222(1-2), 323-325 (1994).
11. N. Komatsu, S. Matsunaga, T. Sugita, and S. Uemura,* "Asymmetric Selenoxide Elimination Leading to Chiral Alkyl and Aryl Cyclohexylidenemethyl Ketones" J. Am. Chem. Soc., 115(13), 5847-5848 (1993).
10. N. Komatsu, T. Murakami, Y. Nishibayashi, T. Sugita, and S. Uemura,* "Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones" J. Org. Chem., 58(14), 3697-3702 (1993).
9. N. Komatsu, M. Hashizume, T. Sugita, and S. Uemura,* "Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides with tert-Butyl Hydroperoxide Using Chiral Binaphthol as a Chiral Auxiliary" J. Org. Chem., 58(17), 4529-4534 (1993).
8. N. Komatsu, M. Hashizume, T. Sugita, and S. Uemura,* "Kinetic Resolution of Sulfoxides Catalyzed by Chiral Titanium-Binaphthol Complex" J. Org. Chem., 58(26), 7624-7626 (1993).
7. Y. Nishibayashi, N. Komatsu, K. Ohe, and S. Uemura,* "Telluroxide Elimination by Oxidation of Alkyl Aryl Tellurides: A Remarkable Effect of Triethylamine Added" J. Chem. Soc., Perkin Trans. 1, (10), 1133-1137 (1993).
6. N. Komatsu, Y. Nishibayashi, and S. Uemura,* "Asymmetric [2,3] Sigmatropic Rearrangement via Chiral Selenoxide with Sharpless Oxidants" Tetrahedron Lett., 34(14), 2339-2342 (1993).
5. N. Komatsu, Y. Nishibayashi, T. Sugita,* and S. Uemura,* "The First Example of Asymmetric Selenoxide Elimination: Application to the Synthesis of Chiral Allenes" J. Chem. Soc., Chem. Commun., (1), 46-47 (1992).
4. N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura,* "Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Using R-(+)-Binaphthol" Tetrahedron Lett., 33(37), 5391-5394 (1992).
3. N. Komatsu, S. Shimizu, and T. Sugita,* "A Reinvestigation of the Beckmann Rearrangement of (-)-Menthon Oxime: Preparation of (+)-(3S, 6R)-3-Isopropyl-6-methylhexahydroazepin-2-one" Synth. Commun., 22(2), 277-279 (1992).
2. T. Sugita,* N. Komatsu, T. Terada, A. Kurihara, and T. Kagiya, "Solvent Effect on Asymmetric Addition of Organometallic Reagents to Homochiral _-Ketoacetals" Chem. Express, 4(11), 717-720 (1989).
1. T. Sugita,* M. Eida, H. Ito, N. Komatsu, K. Abe, and M. Suama, "Regioselectivity of Addition of Thiols and Amines to Conjugated Allenic Ketones and Esters" J. Org. Chem., 52(17), 3789-3793 (1987).